High-pressure real-time (129)Xe NMR: monitoring of surfactant conformation during the self-assembly of reverse micelles in supercritical carbon dioxide.
نویسندگان
چکیده
High-pressure (129)Xe NMR has been used to monitor in real time the self-assembly of reverse water-in-supercritical carbon dioxide micelles in the absence of shear, without the need for sensitivity enhancement techniques such as hyperpolarization.
منابع مشابه
Effect of compressed CO2 on the properties of AOT reverse micelles studied by spectroscopy and phase behavior
Combination of reverse micellar solutions and supercritical or compressed carbon dioxide (CO2) is a new and interesting topic. This work conducted the first study on the effect of compressed CO2 on the micro-properties ~e.g., micropolarity, ionic strength, pH) of the sodium bis~2-ethylhexyl! sulfosuccinate reverse micelles in isooctane by phase behavior measurement, Fourier transform infrared a...
متن کاملContinuous Synthesis of Oleyl Oleate in Supercritical Carbon Dioxide using Solid p-Toluenesulfonic Acid as Catalyst
Supercritical carbon dioxide (SC-CO2) was used as solvent to synthesize oleyl oleate as an analog of Jojoba oil from oleic acid and oleyl alcohol with high conversion (100%) of the acid into ester in a short time of 100 min. Utilizing a low cost solid catalyst, p-toluenesulfonic acid monohydrate (PTSA), the esterification reaction was performed, without any prior preparation step...
متن کاملHigh-efficiency exfoliation of layered materials into 2D nanosheets in switchable CO2/Surfactant/H2O system
Layered materials present attractive and important properties due to their two-dimensional (2D) structure, allowing potential applications including electronics, optoelectronics, and catalysis. However, fully exploiting the outstanding properties will require a method for their efficient exfoliation. Here we present that a series of layered materials can be successfully exfoliated into single- ...
متن کاملPreparation of PMMA/MWNTs Nanocomposite Microcellular Foams by In-situ Generation of Supercritical Carbon Dioxide
Nanocomposites containing poly(methyl methacrylate) (PMMA) and surface functionalized Multi-Walled Carbon Nanotubes (MWNTs) were synthesized. The dispersion of MWNTs in PMMA was characterized using Transmission Electron Microscopy (TEM).The synthesized nanocomposites were successfully foamed using a simple method based on the in-situ generation of supercritical carbon dioxide (CO2</sub...
متن کاملNMR and SANS studies of aggregation and microemulsion formation by phosphorus fluorosurfactants in liquid and supercritical carbon dioxide.
(1)H NMR relaxation and diffusion studies were performed on water-in-CO(2) (W/C) microemulsion systems formed with phosphorus fluorosurfactants of bis[2-(F-hexyl)ethyl] phosphate salts (DiF(8)), having different counterions (Na(+), NH(4)(+), N(CH(3))(4)(+)) by means of high-pressure in situ NMR. Water has a low solubility in CO(2) and is mainly solubilized by the microemulsion droplets formed w...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 46 16 شماره
صفحات -
تاریخ انتشار 2010